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Combine garlic, cayenne pepper, and barbecue sauce in a saucepan and bring to a quick boil. Allow sauce to cool, then add the sesame oil and set aside.
With a sharp knife remove the tips from the chicken wings. Place the wings in a large lock-top baggie and add the sauce mixture. Seal the bag and coat the wings with the sauce.
Refrigerate for about four hours, turning the baggie periodically to coat the wings with sauce. Remove the wings from the baggie and sprinkle with sesame seeds. Pour the remaining marinade into a saucepan and bring to a boil for one minute and remove from the heat.
Grill the chicken wings directly over a medium heat. Turn the wings once with tongs and continue to baste with the boiled marinade for approximately 15 minutes.
Serve the wings warm with additional sauce (or a different sauce/dip/dressing of your choice) for dipping.
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